|Blue to blue-green gel or crystalline powder|
|80° C (176° F)|
SECTION 1. IDENTIFICATION
Product Name: Copper Hydroxide
Product Number: all applicable American facets product codes, e.g. CU-OH-02, CU-OH-025, CU-OH-03, CU-OH-035, CU-OH-04, CU-OH-05
CAS #: 20427-59-2
Relevant determined uses of the substance: scientific research and also development
Emergency call number:Domestic, phibìc America: +1 800-424-9300International: +1 703-527-3887
SECTION 2. Dangers IDENTIFICATION
Classification the the substance or mixture in accordance with 29 CFR 1910 (OSHA HCS)GHS05 CorrosionEye Dam. 1 H318 causes serious eye damage.GHS07Acute Tox. 4 H302 Harmful if swallowed.Skin Irrit. 2H315 reasons skin irritation.STOT SE 3 H335 May reason respiratory irritation.Hazards no otherwise classifiedNo data availableGHS label elementsGHS label elements, including precautionary statementsHazard pictograms
GHS05 GHS07Signal wordDangerHazard statementsH302 Harmful if swallowed.H315 reasons skin irritation.H318 reasons serious eye damage.H335 May reason respiratory irritation.Precautionary statementsP261Avoid breathing dust/fume/gas/mist/vapors/spray.P280Wear safety gloves/protective clothing/eye protection/face protection.P305+P351+P338 IF IN EYES: rinse cautiously v water for number of minutes. Remove contact lenses, if present and easy to do. Continue rinsing.P304+P340IF INHALED: Remove human being to new air and keep comfortable for breathing.P405Store locked up.P501Dispose that contents/container in accordance through local/regional/national/international regulations.WHMIS classificationD2B - toxicity material causing other toxicity effectsClassification systemHMIS ratings (scale 0-4)(Hazardous materials Identification System)Health (acute effects) = 2Flammability = 0Physical hazard = 0Other hazardsResults the PBT and also vPvB assessmentPBT:N/AvPvB:N/A
SECTION 3. COMPOSITION/INFORMATION ~ above INGREDIENTS
SubstancesCAS No. / substance Name:20427-59-2 Copper(II) hydroxideIdentification number(s):EC number: 243-815-9Impurities and stabilizing additives:Stabilizer is present yet may vary.
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SECTION 4. An initial AID MEASURES
Description of very first aid measuresGeneral informationTake impacted persons out into the fresh air.If inhaled:In instance of unconsciousness place patient stably in side position for transportation.Supply patient through fresh air. If no breathing, administer artificial respiration. Save patient warm.Seek prompt medical advice.In case of skin contact:Immediately wash v soap and also water; wash thoroughly.Seek instant medical advice.In instance of eye contact:Rinse opened up eye for numerous minutes under running water. Above a physician.If swallowed:Drink lots of water.Induce vomiting if patient is conscious.Information because that doctorMost necessary symptoms and also effects, both acute and delayedNo data availableIndication of any type of immediate medical attention and special therapy neededNo data available
SECTION 5. FIREFIGHTING MEASURES
Extinguishing mediaSuitable extinguishing agentsCarbon dioxide, extinguishing powder or water spray. Fight larger fires through water spray or alcohol resistant foam.Product is no flammable. Use fire-fighting steps that suit the neighboring fire.Special hazards arising from the problem or mixtureIf this product is connected in a fire, the following can it is in released:Copper oxidesAdvice for firefightersProtective equipment:Wear self-contained respirator.Wear totally protective impervious suit.
SECTION 6. ACCIDENTAL release MEASURES
Personal precautions, security equipment and emergency proceduresUse personal protective equipment. Keep unprotected persons away.Ensure adequate ventilationEnvironmental precautions:Do not allow to get in sewers/ surface or groundwater.Methods and materials because that containment and also cleanup:Prevent formation of dust.Dispose that contaminated product as waste according to ar 13.Ensure sufficient ventilation.Prevention of second hazards:No special steps required.Reference to various other sectionsSee ar 7 for information on safe handlingSee section 8 for information on personal protection equipment.See ar 13 because that disposal information.
SECTION 7. HANDLING and also STORAGE
HandlingPrecautions for safe handlingHandle under dry protective gas.Keep container tightly sealed.Store in cool, dry ar in tightly closeup of the door containers.Ensure great ventilation at the workplace.Information around protection against explosions and also fires:The product is not flammableConditions for safe storage, including any incompatibilitiesRequirements to be met through storerooms and also receptacles:No special requirements.Information about storage in one typical storage facility:Store away from water/moisture.Do no store together with acids.Store away from oxidizing agents.Further information around storage conditions:Store under dried inert gas.This product is hygroscopic.Keep container strict sealed.Store in cool, dry conditions in well-sealed containers.Protect native humidity and water.Specific end use(s)No data available
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Additional information around design of technical systems:Properly operating chemical fume hood designed because that hazardous chemicals and having one average confront velocity of at the very least 100 feet every minute.Control parametersComponents through limit worths that require monitoring in ~ the workplace:None.Additional information:The exposure boundaries that were valid as soon as the MSDS was developed were used.No dataExposure controlsPersonal safety equipmentFollow common protective and also hygienic practices for managing chemicals.Keep far from foodstuffs, beverages and feed.Remove every soiled and contaminated apparel immediately.Wash hands before breaks and at the finish of work.Avoid call with the eyes and also skin.Maintain one ergonomically proper working environment.Breathing equipment:Use an ideal respirator as soon as high concentrations room present.In case of short exposure or low air pollution use respiratory filter device. In case of intensive or much longer exposure use respiratory protective maker that is elevation of turn air.Recommended filter device for short term use:Filter P2Use a respirator with form N95 (USA) or PE (EN 143) cartridges together a backup to engineering controls. Hazard assessment must be performed to determine if air-purifying respirators space appropriate. Just use devices tested and approved under ideal government standards.Protection of hands:Impervious glovesProtective gloves.Inspect gloves before use.Suitability the gloves have to be figured out both by material and quality, the latter of which may vary by manufacturer.Material of glovesNitrile rubber, NBRPenetration time of glove material (in minutes)No data availableEye protection:Tightly sealed gogglesBody protection:Protective work clothing.
SECTION 9. PHYSICAL and also CHEMICAL PROPERTIES
Information on basic physical and also chemical propertiesAppearance:Form: PowderColor: BlueOdor: OdorlessOdor threshold: No data available.pH: N/AMelting point/Melting range: NoneBoiling point/Boiling range: NoneSublimation temperature / start: No data availableFlash point: N/AFlammability (solid, gas)Product is no flammable.Ignition temperature: No data availableDecomposition temperature: No data availableAutoignition: No data available.Danger of explosion: Product go not present an explode hazard.Explosion limits:Lower: No data availableUpper: No data availableVapor pressure: N/ADensity at 20 Â°C (68 Â°F): 3.4 g/cmÂ3 (28.373 lbs/gal)Relative densityNo data available.Vapor densityN/AEvaporation rateN/ASolubility in Water (H2O): InsolublePartition coefficient (n-octanol/water): No data available.Viscosity:Dynamic: N/AKinematic: N/AOther informationNo data available
SECTION 10. STABILITY and REACTIVITY
ReactivityNo data availableChemical stabilityStable under recommended storage conditions.Thermal decomposition / conditions to it is in avoided:Decomposes prior to melting.Possibility that hazardous reactionsReacts with solid oxidizing agentsConditions to avoidNo data availableIncompatible materials:AcidsWater/moistureOxidizing agentsHazardous decomposition products:Metal oxide fumeCopper oxidesAdditional information:Avoid lose of stabilizer.
SECTION 11. TOXICOLOGICAL INFORMATION
Information on toxicological effectsAcute toxicity:Harmful if swallowed.The it is registered of Toxic impacts of chemistry Substances (RTECS) contains acute toxicity data for this substance.LD/LC50 worths that are relevant for classification:OralLD50 1000 mg/kg (rat)Dermal LD50 >3160 mg/kg (rabbit)Skin wake up or corrosion:No irritant effect.Causes skin irritation.Eye wake up or corrosion:Irritating effect.Causes severe eye damage.Sensitization:No sensitizing impacts known.Germ cell mutagenicity:No impacts known.Carcinogenicity:EPA-D: no classifiable regarding human carcinogenicity: inadequate human and also animal proof of carcinogenicity or no data room available.Reproductive toxicity:No results known.Specific target organ device toxicity - recurring exposure:No impacts known.Specific target organ mechanism toxicity - single exposure:May cause respiratory irritation.Aspiration hazard:No impacts known.Subacute to chronic toxicity:No impacts known.Additional toxicological information:To the best of our knowledge the acute and also chronic toxicity the this substance is not totally known.The substance is not subject to classification.
SECTION 12. Eco-friendly INFORMATION
ToxicityAquatic toxicity:No data availablePersistence and also degradabilityNo data availableBioaccumulative potentialNo data availableMobility in soilNo data availableAdditional ecological information:The product has actually not yet been evaluated by the commission because that the review of materials hazardous come water. Till the commission has reached that is verdict, the product is evaluated together hazardous to water (WKG 2) in accordance through the references of the VCI (self-evaluation concept).Do not allow product to reach groundwater, water courses, or sewer systems.Do not enable material come be released to the environment without main permits.Danger to drink water if even small quantities leak into the ground.Avoid transfer into the environment.Results of PBT and also vPvB assessmentPBT:N/AvPvB:N/AOther adverse effectsNo data available
SECTION 13. Handle CONSIDERATIONS
Waste treatment methodsRecommendationConsult main regulations come ensure ideal disposal.Waste disposal an essential number follow to the europe Waste Catalogue:06 04 99Uncleaned packagings:Recommendation:Disposal must be made according to main regulations.
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SECTION 14. Move INFORMATION
UN-NumberDOT, ADN, IMDG, IATAN/AUN proper shipping nameDOT, ADN, IMDG, IATAN/ATransport hazard class(es)DOT, ADR, ADN, IMDG, IATAClassN/APacking groupDOT, IMDG, IATAN/AEnvironmental hazards:N/ASpecial precautions for userN/ATransport in mass according come Annex II of MARPOL73/78 and the IBC CodeN/ATransport/Additional information:DOTMarine Pollutant (DOT):No
SECTION 15. Regulation INFORMATION
Safety, health and environmental regulations/legislation certain for the problem or mixtureGHS GHS brand elements, including precautionary statementsHazard pictogramsGHS05GHS07Signal wordDangerHazard statementsH302 Harmful if swallowed.H315 reasons skin irritation.H318 causes serious eye damage.H335 May cause respiratory irritation.Precautionary statementsP261Avoid breathing dust/fume/gas/mist/vapors/spray.P280Wear security gloves/protective clothing/eye protection/face protection.P305+P351+P338 IF IN EYES: wash cautiously v water for several minutes. Remove call lenses, if present and easy come do. Proceed rinsing.P304+P340IF INHALED: Remove human being to new air and also keep comfortable for breathing.P405Store locked up.P501Dispose that contents/container in accordance with local/regional/national/international regulations.National regulationsAll components of this product are noted in the U.S. Ecological Protection firm Toxic Substances regulate Act chemistry substance Inventory.All components of this product are provided on the Canadian residential Substances perform (DSL).SARA section 313 (specific toxic chemical listings)20427-59-2 Copper(II) hydroxideCalifornia Proposition 65Prop 65 - Chemicals well-known to cause cancerSubstance is not listed.Prop 65 - Developmental toxicitySubstance is no listed.Prop 65 - Developmental toxicity, femaleSubstance is not listed.Prop 65 - Developmental toxicity, maleSubstance is no listed.Information around limitation the use:For use only by technically standard individuals.Other regulations, limitations and also prohibitive regulationsSubstance of really High concern (SVHC) follow to the with Regulations (EC) No. 1907/2006.Substance is no listed.The conditions of constraints according to short article 67 and also Annex XVII that the Regulation (EC) No 1907/2006 (REACH) because that the manufacturing, put on the market and use should be observed.Substance is no listed.Annex XIV that the with Regulations (requiring Authorisation for use)Substance is no listed.Chemical security assessment:A Chemical security Assessment has actually not been lugged out.SECTION 16. Other INFORMATION